No, it doesn't ring a bell Fred. (I should do an internet search, shouldn't I? LOL)

So on the Wiki page for The Outer Limits (1963 TV series) there is a list of similar shows at the end of the article:

It could be Out of the Unknown

Also, I remember when the Daleks first appeared on Dr Who and I was just a kid in primary school, I used to jump up off the couch and cower in the doorway. I used to get really anxious hearing their menacing robot voices, "Exterminate! Exterminate!"