I think the lady you saw could have been Mrs Sylvia Heal M.P.
The list below wass taken from www.politicallinks.co.uk
The Speaker Rt Hon Michael Martin MP Principal Deputy Speaker Chairman of Ways and Means Rt Hon Sir Alan Haselhurst MP KCB (Con) First Deputy Chairman Mrs Sylvia Heal MP KCB (Lab) Second Deputy Chairman Sir Michael Lord MP KCB (Con)
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sj