I agree that a lot of unexpected rhymes -- especially those made by carrying over a polysyllabic word from one line to the next -- are not only very good rhymes, but often quite clever.   I'm also a fan of the humorously contrived rhymes of Ogden Nash, Tom Lehrer, etc.   If they turn out to be bad puns, that's intended.

Neil Diamond, however, took a beautiful, serious ballad and stuck a nails-on-the-chalkboard, cringeworthy contrived -- and really unneeded -- rhyme in the middle of it by using bad grammar.   He wins the prize in my opinion.

Now Sting (Gordon Sumner) may also be a contender, if only for really s-t-r-e-t-c-h-i-n-g to find a a kinda, sorta, quasi-, close-but-no-cigar rhyme in the song "Wrapped Around Your Finger:"

"You consider me a young apprentice
Caught between the Scylla and Charybdis."

Hmmm.   
Ho-Kay.

Genie