4 May 1972 Richard Moore, in Derry, Northern Ireland, was shot in the face with a rubber bullet, fired by then Captain Charles Innes of the Royal Artillery regiment.
Richard Moore; The Original Rubber Bullet , article by Linda Rodriguez McRobbie from The people v Rubber Bullets    https://rubberbullets.longlead.com/chapter/rubber-bullet-history-northern-ireland

RICHARD MOORE  - The Young'uns       https://www.youtube.com/watch?v=VDNggaE-_b4